Hafner S, Demco D E
Varian Deutschland GmbH, Alsfelderstrasse 6, D-64289 Darmstadt, Germany.
Solid State Nucl Magn Reson. 2002 Sep-Nov;22(2-3):247-74. doi: 10.1006/snmr.2002.0088.
Fast magic-angle spinning (MAS) holds promise for new approaches to pulsed high-resolution NMR in solids where homogeneous interactions dominate. Prerequisite for developing new pulse methods is the understanding of signal encoding by spin interactions under MAS conditions and of interferences between MAS and pulses. This review discusses corresponding strategies and techniques in a coherent way with particular concentration on homonuclear decoupling techniques for line-narrowing in solids.
快速魔角旋转（MAS）为固体中以均匀相互作用为主导的脉冲高分辨率核磁共振提供了新方法。开发新脉冲方法的前提是理解MAS条件下自旋相互作用的信号编码以及MAS与脉冲之间的干扰。本综述以连贯的方式讨论了相应的策略和技术，特别关注用于固体谱线变窄的同核去耦技术。
