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用于细菌电化学灭活的彩色导电涂料电极的制备

Preparation of a colored conductive paint electrode for electrochemical inactivation of bacteria.

作者信息

Lim Tae-Kyu, Murakami Tadataka, Tsuboi Makoto, Yamashita Kazuharu, Matsunaga Tadashi

机构信息

Department of Biotechnology, Tokyo University of Agriculture & Technology, Koganei, Tokyo 184-8588, Japan.

出版信息

Biotechnol Bioeng. 2003 Feb 5;81(3):299-304. doi: 10.1002/bit.10469.

Abstract

In this study we describe the preparation of a colored conductive paint electrode containing In(2)O(3), SnO(2), or TiO(2) for the electrochemical inactivation of marine bacteria. When each colored conductive paint electrode was immersed in seawater containing 10(6) cells/mL for 90 min, marine microbe attachment to the TiO(2)/SnO(2)/Sb electrode surface was minimal. Preparation of electrodes coated with 40% particles is shown to be more cost-effective, and because of their more translucent coatings they can be painted over with bright colors. When a potential of 1.0 V was applied for 30 min to the colored conductive paint electrode (40 wt% TiO(2)/SnO(2)/Sb) in sterile seawater, the survival ratio decreased to 55%. When 1.5 V vs. saturated calomel electrode (SCE) was applied, all attached cells were inactivated. Chlorine was not detected below an applied potential of 1.5 V. A change in pH was not observed in the range of 0 to 1.5 V. This method might be effective for preventing bacterial cell accumulation and the formation of biofilms.

摘要

在本研究中,我们描述了一种用于海洋细菌电化学灭活的含In(2)O(3)、SnO(2)或TiO(2)的彩色导电涂料电极的制备方法。当将每个彩色导电涂料电极浸入含有10(6)个细胞/毫升的海水中90分钟时,海洋微生物在TiO(2)/SnO(2)/Sb电极表面的附着极少。结果表明,制备涂覆有40%颗粒的电极更具成本效益,并且由于其涂层更半透明,它们可以涂上鲜艳的颜色。当在无菌海水中对彩色导电涂料电极(40 wt% TiO(2)/SnO(2)/Sb)施加1.0 V的电势30分钟时,存活率降至55%。当施加相对于饱和甘汞电极(SCE)为1.5 V的电势时,所有附着的细胞均被灭活。在低于1.5 V的施加电势下未检测到氯。在0至1.5 V的范围内未观察到pH值的变化。该方法可能对防止细菌细胞积聚和生物膜形成有效。

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