Isse Abdirisak A, Gennaro Armando
Dipartimento di Chimica Fisica, Università di Padova, via Loredan 2, 35131 Padova, Italy.
Chem Commun (Camb). 2002 Dec 7(23):2798-9. doi: 10.1039/b206746c.
Silver exhibits powerful electrocatalytic activities towards the reductive carboxylation of benzyl chlorides (RCl): in CO2-saturated CH3CN, reduction of RCl occurs at potentials that are about 0.6 V more positive than those of the same process at Hg or carbon electrodes and gives carboxylic acids in good to excellent yields.