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在Sr-Rh-O体系中稳定(A3A'BO6)α(A3B3O0)β同系新成员的策略：一维(α = 3, β = 2) [Sr10(Sr0.5Rh1.5)TP(Rh6)Oh])24氧化物的结构

Strategies to stabilize new members of the (A3A'BO6)alpha (A3B3O0)beta homologous series in the Sr-Rh-O system: structure of the one-dimensional (alpha = 3, beta = 2) [Sr10(Sr0.5Rh1.5)TP(Rh6)Oh])24 oxide.

作者信息

Boulahya Khalid, Hernando María, Varela Aurea, González-Calbet José M, Parras Marina, Amador Ulises

机构信息

Dpto. Química Inorgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Spain.

出版信息

Chemistry. 2002 Nov 4;8(21):4973-9. doi: 10.1002/1521-3765(20021104)8:21<4973::AID-CHEM4973>3.0.CO;2-6.

DOI:10.1002/1521-3765(20021104)8:21<4973::AID-CHEM4973>3.0.CO;2-6
PMID:12487134
Abstract

The (alpha =3, beta =2) member of the (A3ABO6) (A3B3O9) homologous series has been stabilised in the Sr-Rh-O system for a [Sr10(Sr0.5Rh1.5)TP(Rh6)Oh]O24 composition. The structural characterisation has been performed by powder X-ray and electron diffraction measurements and high-resolution electron microscopy. In this structure, three face-sharing [RhO6] octahedra linked by one [Rh/SrO6] trigonal prism comprise the infinite one-dimensional chain that runs parallel to the c axis of a trigonal unit cell (Pc1), with parameters a=9.6411(1) and c=21.2440(4) A.

摘要

(A3ABO6)(A3B3O9)同系物系列中(α =3, β =2)的成员已在Sr-Rh-O体系中以[Sr10(Sr0.5Rh1.5)TP(Rh6)Oh]O24组成得以稳定。通过粉末X射线和电子衍射测量以及高分辨率电子显微镜进行了结构表征。在该结构中，由一个[Rh/SrO6]三角棱柱连接的三个共面[RhO6]八面体构成了平行于三方晶胞c轴（Pc1）延伸的无限一维链，其参数为a = 9.6411(1) 和c = 21.2440(4) Å。

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