Petrucci Elisabetta, Di Palma Luca, Merli Carlo
Dipartimento di Ingegneria Chimica, dei Materiali, delle Materie Prime e Metallurgia, Università di Roma La Sapienza, Via Eudossiana 18, 00184, Roma, Italy.
Ann Chim. 2002 Oct;92(10):1007-13.
The electrochemical oxidation of an atrazine solution obtained from a flushing treatment of a contaminated soil was investigated. The influence of ethanol on atrazine oxidation was studied. Results show that the electrogenerated Fenton's reagent provides a complete degradation of atrazine and its main chlorinated by-products via N-dehalkylation and dechlorination. This process therefore presents an effective alternative to the chemical oxidation treatment which necessarily needs a further biological state.
对受污染土壤冲洗处理后得到的阿特拉津溶液进行了电化学氧化研究。研究了乙醇对阿特拉津氧化的影响。结果表明,电生成的芬顿试剂通过N-脱烷基化和脱氯作用,可使阿特拉津及其主要氯化副产物完全降解。因此,该过程为化学氧化处理提供了一种有效的替代方法,而化学氧化处理必然需要进一步的生物处理阶段。