一种使用双环[3.2.1]辛烷手性砌块合成(+)-雌酮的新方法。
A new route to (+)-estrone using a bicyclo[3.2.1]octane chiral building block.
作者信息
Hanada Keisuke, Miyazawa Norio, Ogasawara Kunio
机构信息
Pharmaceutical Institute, Tohoku University, Sendai, Japan.
出版信息
Chem Pharm Bull (Tokyo). 2003 Jan;51(1):104-6. doi: 10.1248/cpb.51.104.
PMID:12520140
Abstract
A new route to (+)-estrone has been developed starting from the chiral building block having a bicyclo[3.2.1]octane framework based on the inherent stereochemical chemical nature of the chiral building block.
摘要
基于手性砌块固有的立体化学性质，已开发出一条从具有双环[3.2.1]辛烷骨架的手性砌块出发合成（+）-雌酮的新路线。
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