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1997年春季意大利亚得里亚海12种可食用海洋生物中的有机氯农药和多氯联苯

Organochlorine pesticides and polychlorinated biphenyls in 12 edible marine organisms from the Adriatic Sea, Italy, Spring 1997.

作者信息

Di Muccio A, Stefanelli P, Funari E, Barbini D Attard, Generali T, Pelosi P, Girolimetti S, Amendola G, Vanni F, Di Muccio S

机构信息

Laboratory of Applied Toxicology, ISS (Istituto Superiore di Sanità), Viale Regina Elena 299, I-00161 Rome, Italy.

出版信息

Food Addit Contam. 2002 Dec;19(12):1148-61. doi: 10.1080/0265203021000012394.

Abstract

Edible portions of 12 marine organisms from several areas of the Adriatic Sea, Italy, were collected during Spring 1997 and analysed for 32 organochlorine pesticides residues and 27 polychlorobiphenyl congeners. Only eight organochlorine pesticides - hexachlorobenzene (HCB), hexachlorocyclohexane (HCH) isomers, diphenyl-dichloro-trichloroethane (DDT) group, dieldrin - were determined at levels in the range <0.01-19.88 ng g(-1) wet weight, with 1,1'-dichloro-2,2'-bis(4-chlorophenyl)ethylene (DDE) being the more relevant single organochlorine. The contamination by organochlorine pesticides was comparable in organisms from the North, Centre and South Adriatic. Polychlorinated biphenyls (PCBs) were determined at levels in the range <0.05-14.46 ng g(-1), with CB 101, 118, 138, 153, 180 and 187 being more relevant (penta-, hexa- and hepta-chlorinated congeners). The sum of PCBs congeners determined were in the range 1.18-69.05 ng g(-1). The contamination by PCBs is more relevant in organisms from the North Adriatic Sea owing to the antropic discharge from major rivers such as Po and Adige that flow through highly industrialized and densely populated areas.

摘要

1997年春季,采集了来自意大利亚得里亚海多个区域的12种海洋生物的可食用部分,分析了其中32种有机氯农药残留和27种多氯联苯同系物。仅检测到8种有机氯农药——六氯苯(HCB)、六氯环己烷(HCH)异构体、二苯基二氯三氯乙烷(DDT)类、狄氏剂,其含量在<0.01-19.88 ng g(-1)湿重范围内,其中1,1'-二氯-2,2'-双(4-氯苯基)乙烯(DDE)是较为主要的单一有机氯。亚得里亚海北部、中部和南部生物体内有机氯农药的污染程度相当。多氯联苯(PCBs)的含量在<0.05-14.46 ng g(-1)范围内,其中CB 101、118、138、153、180和187更为主要(五氯、六氯和七氯同系物)。所测定的多氯联苯同系物总量在1.18-69.05 ng g(-1)范围内。由于流经高度工业化和人口密集地区的波河和阿迪杰河等主要河流的人为排放,亚得里亚海北部生物体内多氯联苯的污染更为严重。

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