Foster Trina L, Caradonna John P
Department of Chemistry, Boston University, Massachusetts 02215, USA.
J Am Chem Soc. 2003 Apr 2;125(13):3678-9. doi: 10.1021/ja0286268.
The reaction of [Fe22+(H2Hbamb)2(N-MeIm)2], [1], a binuclear, non-heme iron complex, with 2-methyl-1-phenylprop-2-yl hydroperoxide (MPPH) shows that [1] induces heterolytic cleavage of the peroxy O-O bond. Catalytic atom transfer reactions (1:MPPH:PhSMe 1:596:6011) resulted in the highly efficient (99 +/- 1%), catalytic oxidation of phenyl methyl sulfide to phenyl methyl sulfoxide/sulfone (T.N. = 500/11 respectively) and cyclohexane to cyclohexanol/cyclohexanone (T.N. = 230/5 respectively) showing the highly efficient, catalytic capacity of [1] to carry out oxygen insertion chemistry.
双核非血红素铁配合物[Fe₂²⁺(H₂Hbamb)₂(N - MeIm)₂]（[1]）与2 - 甲基 - 1 - 苯基丙 - 2 - 基氢过氧化物（MPPH）的反应表明，[1]能诱导过氧O - O键的异裂。催化原子转移反应（1:MPPH:PhSMe为1:596:6011）导致苯甲硫醚高效（99±1%）催化氧化为苯甲亚砜/苯甲砜（分别为T.N. = 500/11），环己烷氧化为环己醇/环己酮（分别为T.N. = 230/5），这表明[1]具有进行氧插入化学的高效催化能力。
