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一种三维金属有机网络,[Cu2(戊二酸)2(4,4'-联吡啶)],其表现出单晶到单晶的脱水和再水化过程。

A 3D metal-organic network, [Cu2(glutarate)2(4,4'-bipyridine)], that exhibits single-crystal to single-crystal dehydration and rehydration.

作者信息

Rather Beth, Zaworotko Michael J

机构信息

Department of Chemistry, University of South Florida, 4202 E Fowler Ave (SCA400), Tampa, FL 33620, USA.

出版信息

Chem Commun (Camb). 2003 Apr 7(7):830-1. doi: 10.1039/b301219k.

DOI:10.1039/b301219k
PMID:12739633
Abstract

The reaction of Cu(NO3)2, glutaric acid and 4,4'-bipyridine in water affords a novel 3D coordination polymer which exhibits reversible desorption and adsorption of water molecules with retention of single crystallinity.

摘要

硝酸铜、戊二酸和4,4'-联吡啶在水中反应生成一种新型的三维配位聚合物,该聚合物表现出可逆的水分子解吸和吸附,同时保持单晶性。

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