Cohen E. G. D., Rondoni L.
Rockefeller University, New York, New York 10021.
Chaos. 1998 Jun;8(2):357-365. doi: 10.1063/1.166317.
The phase space contraction and the entropy production rates of Hamiltonian systems in an external field, thermostatted to obtain a stationary state, are considered. While for stationary states with a constant kinetic energy the two rates are formally equal for all numbers of particles N, for stationary states with constant total (kinetic and potential) energy this only obtains for large N. However, in both cases a large number of particles is required to obtain equality with the entropy production rate of Irreversible Thermodynamics. Consequences of this for the positivity of the transport coefficients and for the Onsager relations are discussed. Numerical results are presented for the special case of the Lorentz gas. (c) 1998 American Institute of Physics.
考虑在外部场中哈密顿系统的相空间收缩和熵产生率,该系统通过恒温来获得稳态。对于动能恒定的稳态,这两个速率对于所有粒子数(N)在形式上是相等的;而对于总(动能和势能)能量恒定的稳态,这仅在(N)很大时成立。然而,在这两种情况下,都需要大量粒子才能使其与不可逆热力学的熵产生率相等。讨论了这对于输运系数的正性和昂萨格关系的影响。给出了洛伦兹气体特殊情况的数值结果。(c) 1998美国物理研究所。