Reimann Clemens, Bjorvatn Kjell, Frengstad Bjørn, Melaku Zenebe, Tekle-Haimanot Redda, Siewers Ulrich
Geological Survey of Norway, N-7491 Trondheim, Norway.
Sci Total Environ. 2003 Jul 20;311(1-3):65-80. doi: 10.1016/S0048-9697(03)00137-2.
Drinking water samples were collected throughout the Ethiopian part of the Rift Valley, separated into water drawn from deep wells (deeper than 60 m), shallow wells (<60 m deep), hot springs (T>36 degrees C), springs (T<32 degrees C) and rivers. A total of 138 samples were analysed for 70 parameters (Ag, Al, As, B, Ba, Be, Bi, Br, Ca, Cd, Ce, Cl, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Gd, Ge, Hf, Hg, Ho, I, In, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, NO(2), NO(3), Pb, Pr, Rb, Sb, Se, Si, Sm, Sn, SO(4), Sr, Ta, Tb, Te, Th, Ti, Tl, Tm, U, V, W, Y, Yb, Zn, Zr, temperature, pH, conductivity and alkalinity) with ion chromatography (anions), spectrometry (ICP-OES and ICP-MS, cations) and parameter-specific (e.g. titration) techniques. In terms of European water directives and WHO guidelines, 86% of all wells yield water that fails to pass the quality standards set for drinking water. The most problematic element is fluoride (F), for which 33% of all samples returned values above 1.5 mg/l and up to 11.6 mg/l. The incidence of dental and skeletal fluorosis is well documented in the Rift Valley. Another problematic element may be uranium (U)-47% of all wells yield water with concentrations above the newly suggested WHO maximum acceptable concentration (MAC) of 2 microg/l. Fortunately, only 7% of the collected samples are above the 10 microg/l EU-MAC for As in drinking water.
在东非大裂谷的埃塞俄比亚部分地区采集了饮用水样本,这些样本分为从深井(深度超过60米)、浅井(深度小于60米)、温泉(温度>36摄氏度)、泉水(温度<32摄氏度)和河流中抽取的水。总共对138个样本进行了70项参数分析(银、铝、砷、硼、钡、铍、铋、溴、钙、镉、铈、氯、钴、铬、铯、铜、镝、铒、铕、氟、铁、镓、钆、锗、铪、汞、钬、碘、铟、钾、镧、锂、镥、镁、锰、钼、钠、铌、钕、镍、亚硝酸根、硝酸根、铅、镨、铷、锑、硒、硅、钐、锡、硫酸根、锶、钽、铽、碲、钍、钛、铊、铥、铀、钒、钨、钇、镱、锌、锆、温度、pH值、电导率和碱度),采用离子色谱法(分析阴离子)、光谱法(电感耦合等离子体发射光谱法和电感耦合等离子体质谱法,分析阳离子)以及特定参数(如滴定法)技术。根据欧洲水指令和世界卫生组织指南,所有水井中86%的产水不符合饮用水质量标准。最成问题的元素是氟(F),所有样本中有33%的氟含量超过1.5毫克/升,最高达到11.6毫克/升。在裂谷地区,牙齿和骨骼氟中毒的发病率有充分记录。另一个有问题的元素可能是铀(U)——所有水井中有47%的产水铀浓度高于世界卫生组织新建议的2微克/升最大可接受浓度(MAC)。幸运的是,所采集的样本中只有7%超过了欧盟规定的饮用水中砷的10微克/升MAC。