Fielding S M, Olmsted P D
Polymer IRC and Department of Physics & Astronomy, University of Leeds, Leeds LS2 9JT, United Kingdom.
Phys Rev Lett. 2003 Jun 6;90(22):224501. doi: 10.1103/PhysRevLett.90.224501.
We present a unified model of shear-induced demixing and "mechanical" shear banding instabilities in polymeric and surfactant solutions, by combining a simple flow instability with a two-fluid approach to concentration fluctuations. Within this model, we calculate the "spinodal" limit of stability of initially homogeneous shear states to demixing/banding, and predict the selected length and time scales at which inhomogeneity first emerges after a shear start-up "quench" into the unstable region, finding qualitative agreement with experiment. Our analysis is the counterpart, for this driven phase transition, of the Cahn-Hilliard calculation for unsheared fluid-fluid demixing.
我们通过将简单的流动不稳定性与处理浓度涨落的双流体方法相结合,提出了一个关于聚合物和表面活性剂溶液中剪切诱导的分层和“机械”剪切带不稳定性的统一模型。在该模型中,我们计算了初始均匀剪切状态对于分层/带状化的稳定性的“旋节线”极限,并预测了在剪切启动“猝灭”进入不稳定区域后不均匀性首次出现时所选择的长度和时间尺度,发现与实验结果在定性上相符。对于这种受驱动的相变,我们的分析相当于对未剪切的流体 - 流体分层进行的Cahn - Hilliard计算。