Molybdenum-phosphorus triple bond stabilization by ancillary alkoxide ligation: synthesis and structure of a terminal phosphide tris-1-methylcyclohexanoxide complex.
作者信息
Stephens Frances H, Figueroa Joshua S, Diaconescu Paula L, Cummins Christopher C
机构信息
Massachusetts Institute of Technology, Room 2-227, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, USA.
出版信息
J Am Chem Soc. 2003 Aug 6;125(31):9264-5. doi: 10.1021/ja0354317.
PMID:12889934
Abstract
Using alcoholysis, we converted terminal phosphide PMo(N[i-Pr]Ar)3 into a new, monomeric terminal phosphide PMo(OR)3, where R = 1-methylcyclohexyl or 1-adamantyl. Dimerization of the PMo unit was observed upon alcoholysis with 2,6-dimethylphenol, and the dimer [PMo(N[i-Pr]Ar)(O-2,6-C6H3Me2)2]2 was isolated and characterized by X-ray crystallography.
摘要
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