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来自农业环境中未经处理土壤上种植的韭菜(葱属)作物中的有机氯农药残留。

Organochlorine pesticide residues in leek (Allium porrum) crops grown on untreated soils from an agricultural environment.

作者信息

Gonzalez Mariana, Miglioranza Karina S B, Aizpún De Moreno Julia E, Moreno Víctor J

机构信息

Laboratorio de Ecotoxicología, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Mar del Plata, Funes 3350, 7600 Mar del Plata, Argentina.

出版信息

J Agric Food Chem. 2003 Aug 13;51(17):5024-9. doi: 10.1021/jf034349s.

Abstract

Leek (Allium porrum) plants from organic farming were harvested at 15, 59, and 210 days after seed germination. Organochlorine pesticide (OCP) levels were quantified by GC-ECD in vegetative tissues (roots and aerial), bulk soil and rhizosphere. Leek plant bioaccumulate OCPs efficiently in their aerial and root tissues and alter the concentration of the soil where they are grown. OCPs distribution pattern of bulk soil was endosulfans > DDTs > dieldrin, while it was endosulfans > HCHs > DDTs in leek tissues. There were statistically significant declines in DDTs, chlordane, dieldrin, and heptachlor in the rhizosphere, indicating that recalcitrant residues of OCPs may be removed from contaminated soil using leek crops under normal growing conditions. The DDE/DDT and alpha-/gamma-HCH ratios of < 1 would indicate recent inputs of DDT and lindane in the environment. The occurrence of OCPs in this farm could be the result of atmospheric deposition and/or surface runoff of these pesticides.

摘要

对有机种植的韭菜(葱属植物)在种子萌发后的第15天、59天和210天进行收获。通过气相色谱 - 电子捕获检测器(GC - ECD)对营养组织(根和地上部分)、土壤和根际中的有机氯农药(OCP)含量进行定量分析。韭菜植株能够在地上和根部组织中有效地生物累积有机氯农药,并改变其生长土壤中的农药浓度。土壤中有机氯农药的分布模式为硫丹>滴滴涕>狄氏剂,而在韭菜组织中则为硫丹>六氯环己烷>滴滴涕。根际中的滴滴涕、氯丹、狄氏剂和七氯含量有统计学意义的下降,这表明在正常生长条件下,利用韭菜作物可以从受污染土壤中去除难降解的有机氯农药残留。DDE/DDT和α-/γ-六氯环己烷的比例小于1表明环境中近期有滴滴涕和林丹的输入。该农场中有机氯农药的出现可能是这些农药大气沉降和/或地表径流的结果。

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