Potassium dicyanoargentate(I) 1,4,7,10,13,16-hexaoxacyclooctadecane.
作者信息
Schlueter John A, Geiser Urs
机构信息
Materials Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, USA.
出版信息
Acta Crystallogr C. 2003 Aug;59(Pt 8):m325-7. doi: 10.1107/s0108270103014318. Epub 2003 Jul 22.
PMID:12909757
Abstract
The crystal structure of the title compound, K[Ag(CN)(2)].C(12)H(24)O(6), conventionally denoted K(18-crown-6)Ag(CN)(2), where 18-crown-6 is 1,4,7,10,13,16-hexaoxacyclooctadecane, is characterized by closely packed linear chains formed by the coordination of the nitrile N atoms of the Ag(CN)(2) anions to the K(+) cations. The K atoms lie on centers of inversion and are additionally bound to the six O atoms of the crown ether.
摘要
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