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一种新型磷酸钼化合物(NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)].7H2O的合成与光谱表征

[Synthesis and spectral characterization of a new molybdenum phosphate compound (NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)].7H2O].

作者信息

Lin Zheng-zhong, Zhang Han-hui, Huang Chang-cang, Sun Rui-qing, Zheng Xiao-lin

机构信息

Chemistry Department, Fuzhou University, State Key Laboratory of Structural Chemistry, Fuzhou 350002, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2002 Dec;22(6):1048-50.

PMID:12914196
Abstract

The paper reports a new molybdenum phosphate (NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)].7H2O containing Mo(V) which is hydrothermally synthesized and spectrally characterized by FTIR, Raman and UV/Vis DRS. The result indicates long Mo(V)-O bonds and innumerable hydrogen bonds in compound cause the red shift of characteristic vibrations in IR spectrum of title compound.

摘要

该论文报道了一种新的含钼(V)的磷酸钼(NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)].7H2O,它是通过水热合成法制备的,并通过傅里叶变换红外光谱(FTIR)、拉曼光谱和紫外可见漫反射光谱(UV/Vis DRS)进行了光谱表征。结果表明,化合物中长的钼(V)-氧键和大量氢键导致了标题化合物红外光谱中特征振动的红移。

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