Lin Zheng-zhong, Zhang Han-hui, Huang Chang-cang, Sun Rui-qing, Zheng Xiao-lin
Chemistry Department, Fuzhou University, State Key Laboratory of Structural Chemistry, Fuzhou 350002, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2002 Dec;22(6):1048-50.
The paper reports a new molybdenum phosphate (NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)].7H2O containing Mo(V) which is hydrothermally synthesized and spectrally characterized by FTIR, Raman and UV/Vis DRS. The result indicates long Mo(V)-O bonds and innumerable hydrogen bonds in compound cause the red shift of characteristic vibrations in IR spectrum of title compound.
该论文报道了一种新的含钼(V)的磷酸钼(NH3CH2CH2NH3)7H2[NaMo12O30(PO4)2(HPO4)5(H2PO4)].7H2O,它是通过水热合成法制备的,并通过傅里叶变换红外光谱(FTIR)、拉曼光谱和紫外可见漫反射光谱(UV/Vis DRS)进行了光谱表征。结果表明,化合物中长的钼(V)-氧键和大量氢键导致了标题化合物红外光谱中特征振动的红移。