Park Jae-Hong, Choi Euiso, Gil Kyung-Ik
Department of Environmental System Engineering, Korea University, Seoul, Korea.
J Environ Sci Health A Tox Hazard Subst Environ Eng. 2003 Jul;38(7):1389-99. doi: 10.1081/ese-120021133.
Photocatalytic degradation of reactive dye, Red 120, was carried out on TiO2 particles as photocatalyst under UV irradiation. In this experiment, comparison on the removal of reactive dye by photolysis using UV light alone, photocatalyst adsorption using TiO2 alone and photocatalysis using UV light with photocatalysts as well as the effect of experimental parameters such as the number of column employed, intensity of the light, pH and TiO2 dosage affecting the reaction efficiency of photocatalytic degradation of reactive dye in circular type reactor was examined. The results of this indicate that with both UV light illumination and TiO2 present, reactive dye was more effectively eliminated than with either UV or TiO2 alone. Photocatalytic degradation of reactive dye increased linearly with increasing UV light intensity. However, over 18 mW cm(-2) of UV light intensity, the efficiency reached a plateau. The photocatalytic degradation rate was greater in acid media than in alkaline media. Photocatalytic removal efficiency of reactive dye increased with increasing TiO2 dosage. However, over 1.5 g L(-1) of TiO2 dosage, the efficiency reached a plateau.
以TiO₂颗粒为光催化剂,在紫外光照射下对活性染料Red 120进行光催化降解。在本实验中,考察了单独使用紫外光光解、单独使用TiO₂进行光催化剂吸附、使用紫外光与光催化剂进行光催化以及柱数、光强度、pH值和TiO₂用量等实验参数对圆形反应器中活性染料光催化降解反应效率的影响。结果表明,同时存在紫外光照射和TiO₂时,活性染料的去除效果比单独使用紫外光或TiO₂时更有效。活性染料的光催化降解随紫外光强度的增加呈线性增加。然而,当紫外光强度超过18 mW cm⁻²时,效率达到平台期。酸性介质中的光催化降解速率大于碱性介质中的光催化降解速率。活性染料的光催化去除效率随TiO₂用量的增加而提高。然而,当TiO₂用量超过1.5 g L⁻¹时,效率达到平台期。