具有双μ-和μ3-[N(CN)2]桥的二维配位聚合物Co[N(CN)2]2(L) [L = 二氧化吡嗪(pzdo)和2-甲基二氧化吡嗪(mpdo)]中的长程铁磁有序。

Long-range ferromagnetic ordering in two-dimensional coordination polymers Co[N(CN)2]2(L) [L = pyrazine dioxide (pzdo) and 2-methyl pyrazine dioxide (mpdo)] with dual mu- and mu3-[N(CN)2] bridges.

作者信息

Sun Hao-Ling, Gao Song, Ma Bao-Qing, Su Gang

机构信息

College of Chemistry and Molecular Engineering, State Key Laboratory of Rare Earth Materials Chemistry and Applications, PKU-HKU Joint Laboratory on Rare Earth Materials and Bioinorganic Chemistry, Peking University, Beijing 100871, China.

出版信息

Inorg Chem. 2003 Aug 25;42(17):5399-404. doi: 10.1021/ic034202i.

DOI:10.1021/ic034202i

PMID:12924913

Abstract

Two novel coordination polymers of Co(II) with dicyanamide (dca) were obtained by the addition of ancillary ligands of pyrazine dioxide (pzdo) and 2-methyl pyrazine dioxide (mpdo) into the Co-dca binary system, respectively. CoN(CN)(2)(pzdo) (1) crystallizes in the orthorhombic space group of Pnnm (No. 58) with a = 9.4699(5) A, b = 14.9984(3) A, c = 7.4313(7) A, and Z = 4, while CoN(CN)(2)(mpdo) (2) is in the monoclinic space group C2 (No. 5) with a = 16.5391(4) A, b = 9.6065(2) A, c = 7.5001(2) A, beta = 105.779(1) degrees, and Z = 4. Both complexes contain similar two-dimensional triangular Co-dca layers, which offer rare examples of mixed 1,5-mu- and mu(3)-dca bridging coordination polymers with long-range ferromagnetic ordering below ca. 2.5 K.

摘要

通过分别向Co - dca二元体系中加入辅助配体二氧化吡嗪（pzdo）和2 - 甲基二氧化吡嗪（mpdo），得到了两种新型的Co(II)与双氰胺（dca）的配位聚合物。CoN(CN)(2)(pzdo)（1）结晶于正交空间群Pnnm（编号58），a = 9.4