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污水处理中的温室气体排放:工艺选择是主要因素。

Greenhouse gas production in wastewater treatment: process selection is the major factor.

作者信息

Keller J, Hartley K

机构信息

Advanced Wastewater Management Centre, University of Queensland, St. Lucia, QLD 4072, Australia.

出版信息

Water Sci Technol. 2003;47(12):43-8.

Abstract

Many practical design and operating decisions on wastewater treatment plants can have significant impacts on the overall environmental performance, in particular the greenhouse gas (GHG) emissions. The main factor in this regard is the use of aerobic or anaerobic treatment technology. This paper compares the GHG production of a number of case studies with aerobic or anaerobic main and sludge treatment of domestic wastewater and also looks at the energy balances and economics. This comparison demonstrates that major advantages can be gained by using primarily anaerobic processes as it is possible to largely eliminate any net energy input to the process, and therefore the production of GHG from fossil fuels. This is achieved by converting the energy of the incoming wastewater pollutants to methane which is then used to generate electricity. This is sufficient to power the aerobic processes as well as the mixing etc. of the anaerobic stages. In terms of GHG production, the total output (in CO2 equivalents) can be reduced from 2.4 kg CO2/kg COD(removed) for fully aerobic treatment to 1.0 kg CO2/kg COD(removed) for primarily anaerobic processes. All of the CO2 produced in the anaerobic processes comes from the wastewater pollutants and is therefore greenhouse gas neutral, whereas up to 1.4 kg CO2/kg COD(removed) originates from power generation for the fully aerobic process. This means that considerably more CO2 is produced in power generation than in the actual treatment process, and all of this is typically from fossil fuels, whereas the energy from the wastewater pollutants comes primarily from renewable energy sources, namely agricultural products. Even a change from anaerobic to aerobic sludge treatment processes (for the same aerobic main process) has a massive impact on the CO2 production from fossil fuels. An additional 0.8 kg CO2/kg COD(removed) is produced by changing to aerobic sludge digestion, which equates for a typical 100,000 EP plant to an additional production of over 10 t CO2 per day. Preliminary cost estimates confirm that the largely anaerobic process option is a fully competitive alternative to the mainly aerobic processes used, while achieving the same effluent quality.

摘要

许多关于污水处理厂的实际设计和运营决策可能会对整体环境绩效产生重大影响,尤其是温室气体(GHG)排放。这方面的主要因素是好氧或厌氧处理技术的使用。本文比较了一些采用好氧或厌氧主要及污泥处理工艺处理生活污水的案例研究中的温室气体产生情况,还研究了能量平衡和经济性。这种比较表明,主要采用厌氧工艺可获得重大优势,因为可以在很大程度上消除该工艺的任何净能量输入,从而减少化石燃料产生的温室气体。这是通过将进入的废水污染物的能量转化为甲烷来实现的,然后甲烷用于发电。这足以满足好氧工艺以及厌氧阶段的混合等需求。就温室气体产生而言,总排放量(以二氧化碳当量计)可以从完全好氧处理的2.4千克二氧化碳/千克化学需氧量(去除量)降至主要采用厌氧工艺的1.0千克二氧化碳/千克化学需氧量(去除量)。厌氧工艺中产生的所有二氧化碳均来自废水污染物,因此是温室气体中性的,而完全好氧工艺中高达1.4千克二氧化碳/千克化学需氧量(去除量)的二氧化碳源自发电。这意味着发电过程中产生的二氧化碳比实际处理过程中多得多,而且所有这些通常都来自化石燃料,而废水污染物的能量主要来自可再生能源,即农产品。即使是从厌氧污泥处理工艺改为好氧污泥处理工艺(对于相同的好氧主要工艺),也会对化石燃料产生的二氧化碳产生巨大影响。改为好氧污泥消化会额外产生0.8千克二氧化碳/千克化学需氧量(去除量),这对于一个典型的100,000当量人口的工厂来说,相当于每天额外产生超过10吨二氧化碳。初步成本估算证实,主要采用厌氧工艺的方案是所使用的主要好氧工艺的完全有竞争力的替代方案,同时能达到相同的出水水质。

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