一种通过使用2,6-二甲基-1,4-苯醌的新型氧化还原缩合反应，从手性叔醇制备反式叔烷基羧酸盐的简便方法。
A convenient method for the preparation of inverted tert-alkyl carboxylates from chiral tert-alcohols by a new type of oxidation-reduction condensation using 2,6-dimethyl-1,4-benzoquinone.
作者信息
Mukaiyama Teruaki, Shintou Taichi, Fukumoto Kentaro
机构信息
Center for Basic Research, The Kitasato Institute, 6-15-5 Toshima, Kita-ku, Tokyo 114-0003, Japan.
出版信息
J Am Chem Soc. 2003 Sep 3;125(35):10538-9. doi: 10.1021/ja0303844.
PMID:12940734
Abstract
Oxidation-reduction condensation using in situ-formed alkoxydiphenylphosphines, 2,6-dimethyl-1,4-benzoquinone, and carboxylic acids provided a new and efficient method for the preparation of inverted tert-alkyl carboxylates from various chiral tertiary alcohols.
摘要
使用原位生成的烷氧基二苯基膦、2,6-二甲基-1,4-苯醌和羧酸进行氧化还原缩合反应，为从各种手性叔醇制备反式叔烷基羧酸盐提供了一种新的有效方法。
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