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[An IR study of ion solvation and association of lithium perchlorate in some organic solvents].

作者信息

Tang J, Xuan X, Wang J, Zhuo K

机构信息

School of Chemical and Environmental Sciences, Henan Normal University, 453002 Xinxiang.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2001 Aug;21(4):472-4.

PMID:12945264
Abstract

The infrared (IR) spectra of propylene carbonate (PC), gamma-butyrolactone (BL) and diethyl carbonate (DEC) in the presence of LiClO4 have been investigated. It is shown that the interactions between Li+ and these solvents occur on the oxygen atoms of the carbonyl of solvent molecules. On the other hand, spectral curve fitting for band shape of perchlorate anion shows the presence of ion association in these solutions.

摘要

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