[磷钼钒氧簇[PMo9V3O40]6-的氧硫杂多阴离子的合成与光谱研究]

[Synthesis and spectroscopic studies of the oxothio heteropolyanion of [PMo9V3O40]6-].

作者信息

Chen D, Zhang H, Yang R, Sun R, Yang Q, Yu X

机构信息

Department of Chemistry, Fuzhou University, 350002 Fuzhou.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2000 Oct;20(5):712-4.

PMID:12945429

Abstract

Some compounds were obtained through addition H2S to the heteropoly-compound (NH4)4H2[PMo9V3O40].10H2O in dimethyformamide. The FTIR spectrum and NIR FT-Raman spectrum of these compounds were investigated. The spectroscopic studies of the compound II showed that it is a oxothio heteropoly-compound.

摘要

通过在二甲基甲酰胺中将硫化氢添加到杂多化合物(NH4)4H2[PMo9V3O40].10H2O中获得了一些化合物。研究了这些化合物的傅里叶变换红外光谱(FTIR)和近红外傅里叶变换拉曼光谱(NIR FT-Raman)。化合物II的光谱研究表明它是一种氧硫杂多化合物。