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Remarkably selective reduction of the alpha,beta-carbon-carbon double bond in highly activated alpha,beta,gamma,delta-unsaturated alkenes by the InCl3-NaBH4 reagent system.

作者信息

Ranu Brindaban C, Samanta Sampak

机构信息

Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta-700 032, India.

出版信息

J Org Chem. 2003 Sep 5;68(18):7130-2. doi: 10.1021/jo0347821.

Abstract

A combination of sodium borohydride and a catalytic amount of indium(III) chloride in acetonitrile reduces exclusively the alpha,beta-carbon-carbon double bond in alpha,beta,gamma,delta-unsaturated diaryl ketones, dicarboxylic ester, cyanoester, and dicyano compounds.

摘要

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