Liang Lan-Chang, Lee Wei-Ying, Hung Chen-Hsiung
Department of Chemistry and Center for Nanoscience & Nanotechnology, National Sun Yat-sen University, Kaohsiung 80424, Taiwan.
Inorg Chem. 2003 Sep 8;42(18):5471-3. doi: 10.1021/ic0346228.
The first examples of amido phosphine complexes of zinc have been prepared. Addition of N-(2-diphenylphosphinophenyl)-2,6-diisopropylaniline (H[NP]) to ZnMe(2) or ZnEt(2) in diethyl ether at -35 degrees C generated the monomeric, three-coordinate [NP]ZnR (R = Me, Et), while the metathesis reaction of ZnCl(2) with [NP]Li(THF)(2) in diethyl ether at -35 degrees C produced homoleptic NPZn.
锌的酰胺基膦配合物的首批实例已被制备出来。在-35℃下于乙醚中，将N-(2-二苯基膦基苯基)-2,6-二异丙基苯胺（H[NP]）添加到ZnMe₂或ZnEt₂中，生成了单体的三配位[NP]ZnR（R = Me，Et），而在-35℃下于乙醚中，ZnCl₂与[NP]Li(THF)₂发生复分解反应则生成了均配物[NP]₂Zn。
