• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

电喷雾电离质谱法在铝（III）-配体溶液平衡研究中的应用

Electrospray ionization mass spectrometry in studies of aluminium(III)-ligand solution equilibria.

作者信息

Di Marco Valerio B, Bombi G Giorgio, Tubaro Michela, Traldi Pietro

机构信息

Università degli Studi di Padova, Dipartimento di Chimica Inorganica, Metallorganica ed Analitica, via Marzolo 1, 35131 Padova, Italy.

出版信息

Rapid Commun Mass Spectrom. 2003;17(18):2039-46. doi: 10.1002/rcm.1147.

DOI:10.1002/rcm.1147
PMID:12955732
Abstract

Electrospray ionization mass spectrometry (ESI-MS) has been applied to the study of solution equilibria between Al(III) and the two ligands 4-hydroxy-3-pyridinecarboxylic acid (4H3P) and 3-hydroxy-4-pyridinecarboxylic acid (3H4P). The results compare well with the speciation data obtained from potentiometric, UV-visible spectroscopy, and NMR measurements. This agreement suggests the applicability of ES-MS to the study of more complicated aluminium-ligand systems.

摘要

电喷雾电离质谱（ESI-MS）已应用于研究铝（III）与两种配体4-羟基-3-吡啶羧酸（4H3P）和3-羟基-4-吡啶羧酸（3H4P）之间的溶液平衡。结果与通过电位滴定法、紫外可见光谱法和核磁共振测量获得的物种形成数据吻合良好。这种一致性表明ESI-MS适用于研究更复杂的铝-配体体系。

相似文献

1
Electrospray ionization mass spectrometry in studies of aluminium(III)-ligand solution equilibria.电喷雾电离质谱法在铝（III）-配体溶液平衡研究中的应用
Rapid Commun Mass Spectrom. 2003;17(18):2039-46. doi: 10.1002/rcm.1147.
2
1,6-Dimethyl-4-hydroxy-3-pyridinecarboxylic acid and 4-hydroxy-2-methyl-3-pyridinecarboxylic acid as new possible chelating agents for iron and aluminium.1,6 - 二甲基 - 4 - 羟基 - 3 - 吡啶甲酸和4 - 羟基 - 2 - 甲基 - 3 - 吡啶甲酸作为铁和铝的新型潜在螯合剂。
Dalton Trans. 2009 Mar 14(10):1815-24. doi: 10.1039/b819148d. Epub 2009 Jan 27.
3
Evaluation of 2-methyl-3-hydroxy-4-pyridinecarboxylic acid as a possible chelating agent for iron and aluminium.评估2-甲基-3-羟基-4-吡啶羧酸作为铁和铝的潜在螯合剂的性能。
Dalton Trans. 2008 Apr 7(13):1689-97. doi: 10.1039/b717269a. Epub 2008 Feb 14.
4
Metal-ligand solution equilibria studied by electrospray ionization mass spectrometry: correlation between ion intensity and acid-base equilibria in solution.通过电喷雾电离质谱研究金属-配体溶液平衡：溶液中离子强度与酸碱平衡之间的相关性。
Rapid Commun Mass Spectrom. 2007;21(23):3825-32. doi: 10.1002/rcm.3292.
5
Iron(III) and aluminum(III) complexes with hydroxypyrone ligands aimed to design kojic acid derivatives with new perspectives.旨在设计具有新视角的曲酸衍生物的含羟基吡喃酮配体的铁（III）和铝（III）配合物。
J Inorg Biochem. 2010 May;104(5):560-9. doi: 10.1016/j.jinorgbio.2010.01.007. Epub 2010 Feb 6.
6
AlIII ion complexes of saccharic acid and mucic acid: a solution and solid-state study.糖二酸和粘酸的铝离子配合物：溶液和固态研究
Chemistry. 2004 Mar 5;10(5):1281-90. doi: 10.1002/chem.200305328.
7
Speciation of Zn-aminopolycarboxylic complexes by electrospray ionization mass spectrometry and ion chromatography with inductively coupled plasma mass spectrometry.通过电喷雾电离质谱法和电感耦合等离子体质谱法离子色谱法对锌-氨基多羧酸配合物进行物种形成分析。
Rapid Commun Mass Spectrom. 2009 Feb;23(3):419-24. doi: 10.1002/rcm.3897.
8
A combined stopped-flow, electrospray ionization mass spectrometry and (31)P NMR study on the acetic acid-mediated fragmentation of the hydroxo-chalcogenide cluster [W(3)Se(4)(OH)(3)(dmpe)(3)](+) (dmpe = 1,2-bis(dimethylphosphanyl)ethane) to yield the dinuclear [W(2)Se(2)(mu-Se)(2)(mu-CH(3)CO(2))(dmpe)(2)](+) complex.一项结合停流、电喷雾电离质谱和（31）P核磁共振的研究，关于乙酸介导的羟基硫族化物簇[W(3)Se(4)(OH)(3)(dmpe)(3)](+)（dmpe = 1,2 - 双（二甲基膦基）乙烷）裂解生成双核[W(2)Se(2)(μ - Se)(2)(μ - CH(3)CO(2))(dmpe)(2)](+)配合物。
Dalton Trans. 2006 Dec 28(48):5725-33. doi: 10.1039/b611274a. Epub 2006 Oct 11.
9
Perturbations produced by electrospray ionization mass spectrometry in the speciation of aluminium(III)/1,6-dimethyl-4-hydroxy-3-pyridinecarboxylate aqueous solutions.电喷雾电离质谱在铝(III)/1,6-二甲基-4-羟基-3-吡啶羧酸水溶液形态分析中产生的扰动。
Rapid Commun Mass Spectrom. 2010 Apr 15;24(7):868-74. doi: 10.1002/rcm.4457.
10
Formation of metal-nicotianamine complexes as affected by pH, ligand exchange with citrate and metal exchange. A study by electrospray ionization time-of-flight mass spectrometry.pH值、与柠檬酸盐的配体交换及金属交换对金属-烟酰胺配合物形成的影响。电喷雾电离飞行时间质谱研究
Rapid Commun Mass Spectrom. 2008 May;22(10):1553-62. doi: 10.1002/rcm.3523.