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石墨炉原子吸收光谱法测定水处理剂中的痕量铅和镉

[Determination of trace Pb and Cd in water treatment reagent by graphite furnace atomic absorption spectrometry].

作者信息

Zheng E, Yu H, Xie H

机构信息

Water Supply Company of Changsha City, 410007 Changsha.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2000 Jun;20(3):379-80.

Abstract

The optimum conditions for the determination of trace Pb and Cd in water treatment reagent by graphite furnace atomic absorption spectrometry were studied in detail in this paper. The results show that the long and tedious pretreatment process was cut down by calibrating background with D2 lamp and NH4H2PO4 as matrix modifier. The determination limits were 0.65 microgram.L-1 and 0.12 microgram.L-1 for (Pb and Cd) and linear ranges were 0-50 micrograms.L-1, 0-20 micrograms.L-1 for Pb and Cd, respectively. Rate of recovery was 90%-110%. This method is accurate, quick and simple, and can be used successfully to determine actual samples.

摘要

本文详细研究了用石墨炉原子吸收光谱法测定水处理剂中痕量铅和镉的最佳条件。结果表明,以D2灯校正背景并使用磷酸二氢铵作为基体改进剂,减少了冗长繁琐的预处理过程。铅和镉的测定限分别为0.65微克·升-1和0.12微克·升-1,线性范围分别为0 - 50微克·升-1和0 - 20微克·升-1。回收率为90% - 110%。该方法准确、快速、简便,可成功用于实际样品的测定。

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