一种前所未有的八重互穿类金刚石型配位聚合物，其包含一个Cu+(4)(RCO2)(4)簇作为连接节点。

An unprecedented 8-fold interpenetrating diamondoid-like coordination polymer containing a Cu+(4)(RCO2)(4) cluster as connecting node.

作者信息

Wang Xi-Sen, Zhao Hong, Qu Zhi-Rong, Ye Qiong, Zhang Jing, Xiong Ren-Gen, You Xiao-Zeng, Fun Hoong-Kun

机构信息

Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China.

出版信息

Inorg Chem. 2003 Sep 22;42(19):5786-8. doi: 10.1021/ic0344620.

DOI:10.1021/ic0344620

PMID:12971741

Abstract

The reaction of Cu(I)(CH(3)CN)(4)BF(4) with 4-pyridylacrylic acid (4-HPYA) affords an unprecedented 8-fold interpenetrating diamondoid-like coordination polymer network [Cu(I)(3)(4-PYA)(2)(H(2)O)(BF(4)) ] (1) with a Cu(+)(4)(CO(2))(4) cluster as connecting node. The interpenetration in metal coordination polymers is the highest degree ever found within diamondoid nets containing a cluster as connecting note. Its fluorescent property was also reported.

摘要

Cu(I)(CH(3)CN)(4)BF(4) 与 4-吡啶基丙烯酸 (4-HPYA) 反应，得到了一种前所未有的具有 8 重互穿类金刚石型配位聚合物网络 [Cu(I)(3)(4-PYA)(2)(H(2)O)(BF(4)) ] (1)，其以 Cu(+)(4)(CO(2))(4) 簇作为连接节点。金属配位聚合物中的这种互穿现象是在以簇作为连接节点的类金刚石网络中发现的最高程度。还报道了它的荧光性质。