Kasai Kayoko, Sato Mariko
Department of Science Education, Miyagi University of Education, 149 Aramaki, Aoba-ku, Sendai 980-0845, Japan.
Chem Asian J. 2006 Sep 18;1(3):344-8. doi: 10.1002/asia.200600054.
The reaction of [Cu(CH3CN)4]NO3 or AgNO3 with flexible ligands 1,4-bis(4-pyridylmethyl)-2,3,5,6-tetrafluorobenzene (bpf) or 4,4'-bis(4-pyridylmethyl)-2,2',3,3',5,5',6,6'-octafluorobiphenyl (bpfb) afforded two types of interpenetrating coordination polymers. The structures of [Cu2(bpf)3(NO3)2]n and [Ag2(bpf)3-(NO3)2]n are 2D polyrotaxane networks in which 1D polymeric chains are aligned in a grid. The structure of {[Cu(bpfb)2]NO3}n is a 2D grid polymer with two-fold parallel interpenetration.
[Cu(CH₃CN)₄]NO₃ 或 AgNO₃ 与柔性配体 1,4 - 双(4 - 吡啶甲基)-2,3,5,6 - 四氟苯(bpf) 或 4,4'-双(4 - 吡啶甲基)-2,2',3,3',5,5',6,6'-八氟联苯(bpfb) 反应生成了两种类型的互穿配位聚合物。[Cu₂(bpf)₃(NO₃)₂]ₙ 和 [Ag₂(bpf)₃-(NO₃)₂]ₙ 的结构是二维聚轮烷网络，其中一维聚合物链排列成网格状。{[Cu(bpfb)₂]NO₃}ₙ 的结构是具有双重平行互穿的二维网格聚合物。
