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三嗪类除草剂在土壤上的吸附及其热力学性质的相关性

Adsorption and correlation with their thermodynamic properties of triazine herbicides on soils.

作者信息

Yang Wei-chun, Liu Wei-ping, Liu Hui-jun, Liu Guang-shen

机构信息

Institute of Environmental Science, Zhejiang University, Hangzhou 310027, China.

出版信息

J Environ Sci (China). 2003 Jul;15(4):443-8.

Abstract

Adsorption of atrazine, prometryne and prometon was determined on six soils with different physical and chemical properties. The adsorption isotherms of three herbicides could well fit Freundlich equation. On all of six soils, adsorption of herbicides increased in the order: atrazine approximately = prometon < prometryne. This order is quite the same to the calculation result of by means of excess thermodynamic properties of triazine. The Freundlich adsorption constants, Kf, showed to have good correlation with organic matter (OM%) of soils for each of these herbicides, suggesting that OM is the main factor, which dominates in the adsorption process of these triazine herbicides.

摘要

研究了莠去津、扑草净和扑灭通在六种理化性质不同的土壤上的吸附情况。三种除草剂的吸附等温线均能很好地拟合弗伦德里希方程。在所有六种土壤上,除草剂的吸附量按以下顺序增加:莠去津≈扑灭通<扑草净。该顺序与通过三嗪过量热力学性质计算的结果完全相同。弗伦德里希吸附常数Kf表明,每种除草剂与土壤中的有机质(OM%)都有良好的相关性,这表明有机质是这些三嗪类除草剂吸附过程中的主要主导因素。

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