Demchenko A P
FEBS Lett. 1992 Oct 5;310(3):211-5. doi: 10.1016/0014-5793(92)81334-i.
Biocatalytic reactions can occur according to two very different mechanisms: homogeneous, which is described by standard transition state theory (TST) and its modifications, and inhomogeneous (polychromatic), which is characteristic for some of the charge-transfer reactions in liquids and amorphous solids. While most data published on enzyme reactions are interpreted on the basis of homogeneous kinetics, the important recent findings suggest the involvement of inhomogeneous kinetics mechanism.
均相反应，由标准过渡态理论（TST）及其修正理论描述；非均相（多色）反应，这是液体和非晶态固体中某些电荷转移反应的特征。虽然大多数关于酶反应发表的数据是基于均相动力学进行解释的，但最近的重要发现表明非均相动力学机制也参与其中。
