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防护手套对牙科树脂材料中(二)甲基丙烯酸酯的渗透性。

Permeability of protective gloves to (di)methacrylates in resinous dental materials.

作者信息

Munksgaard E C

机构信息

Department of Dental Materials & Technology, Royal Dental College, Copenhagen, Denmark.

出版信息

Scand J Dent Res. 1992 Jun;100(3):189-92. doi: 10.1111/j.1600-0722.1992.tb01739.x.

Abstract

Dentists may develop contact allergy induced by handling resinous dental materials, and vinyl and latex gloves may provide protection against the monomers of these materials only during the time it takes for a monomer to permeate the glove. The passage times and rates of penetration of four commonly used (di)methacrylates--HEMA, TEGDMA, BISGMA, and UEDMA--for 11 protective gloves were measured. The passage time for HEMA and TEGDMA through vinyl gloves was 1-3 min, and around 20 min for BISGMA and UEDMA. The rate of penetration of HEMA and TEGDMA in vinyl gloves was 0.5-4.5 mumol.min-1.cm-2. The passage time of HEMA and TEGDMA through most of the latex or the modified latex gloves was 5-8 min and the rate of penetration 0.5-3.1 mumol.min-1.cm-2. Latex or modified latex gloves provide a protection against BISGMA and UEDMA for 80 min or more with one exception (Elastyrene), which burst after about 50 min in contact with the resins. Of the tested gloves Ansell, Neutralon, Mediglove, and Biogel D provide protection against HEMA and TEGDMA for at least 5 min.

摘要

牙医在处理树脂类牙科材料时可能会引发接触性过敏,乙烯基手套和乳胶手套仅在单体渗透手套所需的时间内,才能为牙医提供针对这些材料单体的防护。对11种防护手套,测量了四种常用(二)甲基丙烯酸酯——甲基丙烯酸羟乙酯(HEMA)、三乙二醇二甲基丙烯酸酯(TEGDMA)、双酚A二甲基丙烯酸缩水甘油酯(BISGMA)和二甲基丙烯酸脲烷乙酯(UEDMA)——的渗透时间和速率。HEMA和TEGDMA透过乙烯基手套的时间为1 - 3分钟,而BISGMA和UEDMA透过乙烯基手套的时间约为20分钟。HEMA和TEGDMA在乙烯基手套中的渗透速率为0.5 - 4.5 μmol·min⁻¹·cm⁻²。HEMA和TEGDMA透过大多数乳胶或改性乳胶手套的时间为5 - 8分钟,渗透速率为0.5 - 3.1 μmol·min⁻¹·cm⁻²。乳胶或改性乳胶手套对BISGMA和UEDMA可提供80分钟或更长时间的防护,只有一个例外(弹性苯乙烯),它与树脂接触约50分钟后破裂。在测试的手套中,安塞尔(Ansell)、纽卓龙(Neutralon)、美迪手套(Mediglove)和生物凝胶D(Biogel D)对HEMA和TEGDMA至少能提供5分钟的防护。

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