Castle L, Hedgcock S E, Kwiatkowska C A, Sharman M, Smith I D
Ministry of Agriculture, Fisheries and Food, Food Science Laboratory, Colney, Norwich, UK.
Food Addit Contam. 1992 Jan-Feb;9(1):11-7. doi: 10.1080/02652039209374043.
Karl Fischer titration has been used to eliminate the need to humidity-condition food contact plastics under test for overall migration into olive oil. The water content of the oil is measured before and after the migration test. This direct measure of the loss (or uptake) of water by the test plastic is then used in calculations of the overall migration. The use of Karl Fischer titration gives faster analysis with reduced labour input. The time savings varied from a few days to several weeks depending on the type of plastic. Karl Fischer titration is particularly useful in the high temperature testing of polar plastics where incomplete humidity conditioning can lead to erroneous results. The technique should be equally valuable when employing sunflower oil or the triglyceride HB307 in place of olive oil.
卡尔费休滴定法已被用于消除对用于测试向橄榄油中整体迁移的食品接触塑料进行湿度调节的需求。在迁移测试前后测量油中的水分含量。然后,将这种对测试塑料中水分损失(或吸收)的直接测量用于整体迁移的计算。使用卡尔费休滴定法可实现更快的分析,同时减少劳动力投入。根据塑料的类型,节省的时间从几天到几周不等。卡尔费休滴定法在极性塑料的高温测试中特别有用,因为湿度调节不完全可能导致错误的结果。当使用葵花籽油或甘油三酯HB307代替橄榄油时,该技术同样具有价值。