SCHWARTZ M, CASE C T
Biophys J. 1964 Mar;4(2):137-49. doi: 10.1016/s0006-3495(64)86774-6.
At relatively high currents, fused anion-cation membranes give rise to rectifying and reactive effects. The rectification becomes less pronounced with increasing frequency. This effect results from changes in the concentration profiles of the ions during the positive and negative phases of the AC cycle. With reduction of the current, the voltage-current response becomes linear. The reactive effect can then be separated from the rectifying effect. The former effect can be attributed essentially to two factors: (a) the presence of transition regions of fixed charge and (b) the diffusion mechanism of the ions in an AC field. The first factor is largely frequency-independent and the second, frequency-dependent. A first approximation equivalent circuit is described. This circuit involves frequency-dependent elements.
在相对较高的电流下，熔融的阴离子-阳离子膜会产生整流和电抗效应。随着频率增加，整流作用变得不那么明显。这种效应是由交流周期正负相中离子浓度分布的变化引起的。随着电流减小，电压-电流响应变为线性。然后可以将电抗效应与整流效应分离。前一种效应主要可归因于两个因素：(a) 固定电荷过渡区的存在和 (b) 离子在交流电场中的扩散机制。第一个因素在很大程度上与频率无关，第二个因素与频率有关。描述了一个一阶近似等效电路。该电路包含与频率相关的元件。
