Taira M, Lautenschlager E P
Division of Biological Materials, Northwestern University, Chicago, Illinois 60611.
J Biomed Mater Res. 1992 Sep;26(9):1131-9. doi: 10.1002/jbm.820260903.
The corrosion resistance of 316L cold worked stainless steel depends upon its thin protective oxide layer; and if this is partially broken down, corrosion resistance depends upon its tendency for repassivation. Since the intended function of stainless-steel implants is to sustain musculoskeletal forces, research toward the stability of the oxide film during dynamic loading in simulated bodylike fluids is warranted. A pilot corrosion fatigue study was, therefore, performed on uniaxial tension fatigue specimens cycled to various maximum stress levels near their yield point while immersed in 37 degrees C isotonic saline solution, and combined with the electrochemical insult of (a) imparting an 800 mV vs. SCE anodic potential for 20 s to stimulate local film breakdown, and then (b) returning to a constant 200 mV vs. SCE anodic potential and maintaining that potential during cyclic loading until the specimens broke in two. During the anodic polarization by continuously monitoring the current it was possible to (a) observe the repassivation and corrosion behavior following stimulation, and (b) detect crack initiation, crack propagation and failure onset. The combined effects of accelerated corrosion and mechanical fatiguing disturbed the repassivation tendency and reduced the crack initiation times and the fatigue lives as compared to air and saline controls. As the maximum cyclic load levels were increased, the fatigue lives were further foreshortened.
316L 冷加工不锈钢的耐腐蚀性取决于其薄的保护性氧化层;如果该氧化层部分被破坏,其耐腐蚀性则取决于再钝化的倾向。由于不锈钢植入物的预期功能是承受肌肉骨骼力量,因此有必要研究在模拟体液的动态加载过程中氧化膜的稳定性。因此,对单轴拉伸疲劳试样进行了一项初步腐蚀疲劳研究,这些试样在浸入 37 摄氏度等渗盐溶液的同时,循环至接近其屈服点的各种最大应力水平,并结合以下电化学损伤:(a) 施加相对于饱和甘汞电极(SCE)为 800 mV 的阳极电位 20 秒,以刺激局部膜破坏,然后 (b) 回到相对于 SCE 恒定的 200 mV 阳极电位,并在循环加载期间保持该电位,直至试样断裂成两半。在阳极极化过程中,通过连续监测电流,可以 (a) 观察刺激后的再钝化和腐蚀行为,以及 (b) 检测裂纹萌生、裂纹扩展和失效起始。与空气和盐水对照相比,加速腐蚀和机械疲劳的综合作用扰乱了再钝化趋势,缩短了裂纹萌生时间和疲劳寿命。随着最大循环载荷水平的增加,疲劳寿命进一步缩短。