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A simple one-pot method for the synthesis of partially protected mono- and disaccharide building blocks using an orthoesterification-benzylation-orthoester rearrangement approach.

作者信息

Mukhopadhyay Balaram, Field Robert A

机构信息

Centre for Carbohydrate Chemistry, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich NR4 7TJ, UK.

出版信息

Carbohydr Res. 2003 Sep 26;338(20):2149-52. doi: 10.1016/s0008-6215(03)00349-5.

DOI:10.1016/s0008-6215(03)00349-5
PMID:14505883
Abstract

A simple one-pot method is reported for making partially protected glycosyl acceptors from O-methyl or S-alkyl/aryl glycosides of D-glucose, D-galactose, D-arabinose, L-rhamnose, L-fucose and lactose via orthoester formation, benzylation and selective hydrolysis.

摘要

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