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茄丝核菌AG-1-IA和IB从薄荷醇生物制备(-)-(1S,3R,4S,6S)-6-羟基薄荷醇和(-)-(1S,3R,4S)-1-羟基薄荷醇

Biopreparation of (-)-(1S,3R,4S,6S)-6-hydroxymenthol and (-)-(1S,3R,4S)-1-hydroxymenthol from 1-menthol by Rhizoctonia solani AG-1-IA and IB.

作者信息

Miyazawa Mitsuo, Kawazoe Hideki, Hyakumachi Mitsuro

机构信息

Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, Kowakae, Higashiosaka-shi, Osaka 577-8502, Japan.

出版信息

Nat Prod Res. 2003 Oct;17(5):307-11. doi: 10.1080/1057563031000072532.

DOI:10.1080/1057563031000072532
PMID:14526907
Abstract

Microbial transformation of 1-menthol (1) by six isolates of soil-borne plant pathogenic fungi Rhizoctonia solani AG-1-IA (Rs24, Joichi-2 and RRG97-1) and AG-1-IB (TR22, R147 and 110.4) as a biocatalyst was investigated. Twenty one days precultivation of Rhizoctonia solani AG-1-IA Rs24 and AG-1-IB 110.4 showed excellent yield (98.5-98.6%) of (-)-(1S,3R,4S,6S)-6-hydroxymenthol (2) and (-)-(1S,3R,4S)-1-hydroxymenthol (3) from 1.

摘要

研究了土壤传播的植物病原真菌立枯丝核菌AG-1-IA（Rs24、上池2号和RRG97-1）和AG-1-IB（TR22、R147和110.4）的六个分离株作为生物催化剂对1-薄荷醇（1）的微生物转化。对立枯丝核菌AG-1-IA Rs24和AG-1-IB 110.4进行21天的预培养，结果显示从1出发，（-）-（1S，3R，4S，6S）-6-羟基薄荷醇（2）和（-）-（1S，3R，4S）-1-羟基薄荷醇（3）的产率极高（98.5-98.6%）。

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