Ferromagnetic behavior of formyl-group-carrying stable thioaminyl radicals.
作者信息
Miura Yozo, Nakamura Shogo, Teki Yoshio
机构信息
Department of Applied Chemistry, Graduate School of Engineering, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan.
出版信息
J Org Chem. 2003 Oct 17;68(21):8244-7. doi: 10.1021/jo0300789.
PMID:14535810
Abstract
Four formyl-group-carrying thioaminyl radicals were generated, and one radical could be isolated as radical crystals. Magnetic susceptibility measurements of the isolated radical showed a ferromagnetic regular linear-chain interaction of 2J/k(B) = 3.2 K, which was explained in terms of the X-ray crystallographic results.
摘要
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