Miura Yozo, Nakamura Shogo, Teki Yoshio
Department of Applied Chemistry, Graduate School of Engineering, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan.
J Org Chem. 2003 Oct 17;68(21):8244-7. doi: 10.1021/jo0300789.
Four formyl-group-carrying thioaminyl radicals were generated, and one radical could be isolated as radical crystals. Magnetic susceptibility measurements of the isolated radical showed a ferromagnetic regular linear-chain interaction of 2J/k(B) = 3.2 K, which was explained in terms of the X-ray crystallographic results.
生成了四个携带甲酰基的硫氨基自由基，其中一个自由基可以作为自由基晶体被分离出来。对分离出的自由基进行的磁化率测量显示出2J/k(B)=3.2 K的铁磁规则线性链相互作用，这可以根据X射线晶体学结果来解释。
