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欧洲同步辐射装置BM2光束线上的衍射异常精细结构光谱学。

Diffraction anomalous fine-structure spectroscopy at beamline BM2 at the European Synchrotron Radiation Facility.

作者信息

Renevier H, Grenier S, Arnaud S, Bérar J F, Caillot B, Hodeau J L, Letoublon A, Proietti M G, Ravel B

机构信息

Laboratoire de Cristallographie, Centre National de la Recherche Scientifique, BP 166, F-38042 Grenoble CEDEX 09, France.

出版信息

J Synchrotron Radiat. 2003 Nov 1;10(Pt 6):435-44. doi: 10.1107/s0909049503021332. Epub 2003 Oct 10.

Abstract

Diffraction anomalous fine-structure (DAFS) spectroscopy uses resonant elastic X-rays scattering as an atomic, shell and site-selective probe that provides information on the electronic structure and the local atomic environment as well as on the long-range-ordered crystallographic structure. A DAFS experiment consists of measuring the Bragg peak intensities as a function of the energy of the incoming X-ray beam. The French CRG (Collaborative Research Group) beamline BM2-D2AM (Diffraction Diffusion Anomale Multi-longueurs d'Onde) at the ESRF (European Synchrotron Radiation Facility) has developed a state-of-the-art energy scan diffraction set-up. In this article the requirements for obtaining reliable DAFS data are presented and recent technical achievements are reported.

摘要

衍射异常精细结构(DAFS)光谱学利用共振弹性X射线散射作为一种原子、壳层和位点选择性探针,它能提供有关电子结构、局部原子环境以及长程有序晶体结构的信息。一次DAFS实验包括测量作为入射X射线束能量函数的布拉格峰强度。法国CRG(合作研究小组)位于欧洲同步辐射装置(ESRF)的BM2-D2AM(多波长异常衍射散射)光束线已经开发出了一种最先进的能量扫描衍射装置。本文介绍了获得可靠DAFS数据的要求,并报告了最近的技术成果。

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