Diéguez Sandra C, De La Peña Ma Luisa G, Gómez Esperanza F
Departamento de Química Analítica y Alimentaria, Area de Química Analítica, Universidad de Vigo, Facultad de Ciencias, As Lagoas s/n, 32004 Ourense, Spain.
J Agric Food Chem. 2003 Dec 3;51(25):7385-90. doi: 10.1021/jf0302916.
Terpenes and C(13) norisoprenoids are among the most important aromatic compounds found in a volatile and nonvolatile form in grapes. Aromatic typicity of a spirit could be attributed to these compounds despite the very important presence of volatile compounds produced during alcoholic fermentation. In this study, following a solid phase extraction stage, the determination of the varietal aromatic compounds by gas chromatography was performed on 15 samples of Galician orujo spirits. The results show that significant differences (p < 0.05) exist in the concentrations of varietal aromatic compounds in Galician spirits obtained from different varieties of grapes. alpha-Ionona is the varietal aromatic compound that is most likely to contribute to the aroma of all of the spirits studied. The spirits from Catalan Roxo are the most aromatic, with floral and fruity nuances, while the spirits from Godello were the less aromatic group as far as the varietal compounds studied are concerned. Spirits from Mencia and Treixadura show a similar profile, but the former has a more intensive aroma due to beta-pinene, citronellol, and alpha-ionone. Albariño spirits stand out because of their profile that is marked by the contributions of eugenol and linalool.
萜类化合物和C(13) 去甲异戊二烯类化合物是葡萄中以挥发性和非挥发性形式存在的最重要的芳香化合物之一。尽管酒精发酵过程中产生的挥发性化合物非常重要,但一种烈酒的芳香典型性可能归因于这些化合物。在本研究中,经过固相萃取阶段后,采用气相色谱法对15个加利西亚葡萄渣白兰地样品中的品种芳香化合物进行了测定。结果表明,从不同品种葡萄获得的加利西亚烈酒中,品种芳香化合物的浓度存在显著差异(p < 0.05)。α-紫罗酮是最有可能对所有研究的烈酒香气产生贡献的品种芳香化合物。来自加泰罗尼亚罗克索葡萄的烈酒香气最为浓郁,带有花香和果香的细微差别,而就所研究的品种化合物而言,戈德洛葡萄制成的烈酒是香气较淡的一组。门西亚和特雷夏杜拉葡萄制成的烈酒表现出相似的特征,但由于β-蒎烯、香茅醇和α-紫罗酮的存在,前者的香气更为浓郁。阿尔巴利诺葡萄制成的烈酒因其丁香酚和芳樟醇的贡献而脱颖而出。