Stacking of molecules possessing a fullerene apex and a cup-shaped cavity connected by a silicon connection.
作者信息
Matsuo Yutaka, Muramatsu Ayako, Hamasaki Ryo, Mizoshita Norihiro, Kato Takashi, Nakamura Eiichi
机构信息
Department of Chemistry, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
出版信息
J Am Chem Soc. 2004 Jan 21;126(2):432-3. doi: 10.1021/ja038816y.
PMID:14719917
Abstract
Hexagonal or tetragonal packing of columnar stacks in crystals and liquid crystals has been observed for a series of molecules possessing a fullerene apex and an aromatic cone that are connected with a Si-C connection. The columnar stacking of the new shuttlecock molecules is constitutionally stable but conformationally flexible due to the large cavity created on the top of the fullerene molecule.
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