Kommana Praveen, Satish Kumar N, Vittal Jagadese J, Jayasree E G, Jemmis E D, Kumara Swamy K C
School of Chemistry, University of Hyderabad, Hyderabad--500046, A. P., India.
Org Lett. 2004 Jan 22;6(2):145-8. doi: 10.1021/ol035990i.
[structure: see text] The sterically bulky tert-butyl group occupies an apical position in trigonal bipyramidal phosphorus in the compound [CH2(6-t-Bu-4-Me-C6H2O)2]P(t-Bu)(1,2-O2C6Cl4) in contrast to the occupation of an equatorial position by the small methyl group in [CH2(6-t-Bu-4-Me-C6H2O)2]P(Me)(1,2-O2C6Cl4); this observation contradicts the familiar "apicophilicity rules" for trigonal bipyramidal phosphorus. Low-temperature solution 31P NMR spectra of [CH2(6-t-Bu-4-Me-C6H2O)2]P(R)(1,2-O2C6Cl4) (R = Me, Et, and n-Bu) show the presence of more than two isomers.