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A general entry to linear, dendritic and branched thiourea-linked glycooligomers as new motifs for phosphate ester recognition in water.

作者信息

Jiménez Blanco José L, Bootello Purificación, Ortiz Mellet Carmen, Gutiérrez Gallego Ricardo, García Fernández José M

机构信息

Departamento de Química Orgánica, Facultad de Química, Universidad de Sevilla, Apartado 553, E-41071 Sevilla, Spain.

出版信息

Chem Commun (Camb). 2004 Jan 7(1):92-3. doi: 10.1039/b312743p. Epub 2003 Nov 18.

DOI:10.1039/b312743p
PMID:14737347
Abstract

A blockwise iterative synthetic strategy for the preparation of linear, dendritic and branched full-carbohydrate architectures has been developed by using sugar azido(carbamate) isothiocyanates as key templates; the presence of intersaccharide thiourea bridges provides anchoring points for hydrogen bond-directed molecular recognition of phosphate esters in water.

摘要

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