Konno Tsutomu, Takehana Tsuyoshi, Ishihara Takashi, Yamanaka Hiroki
Department of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan.
Org Biomol Chem. 2004 Jan 7;2(1):93-8. doi: 10.1039/b310950j. Epub 2003 Nov 17.
The allylic substitution reaction of [small alpha]-fluoroalkylated allyl mesylates with various carbon nucleophiles in the presence of transition metal catalyst (Pd and Mo) proceeded with high regioselectivity to give the corresponding [gamma]-fluoroalkylated products in excellent yields.
在过渡金属催化剂（钯和钼）存在下，[小α]-氟烷基化烯丙基甲磺酸酯与各种碳亲核试剂的烯丙基取代反应以高区域选择性进行，以优异的产率得到相应的[γ]-氟烷基化产物。
