Hindar Atle, Tørseth Kjetil, Henriksen Arne, Orsolini Yvan
Norwegian Institute for Water Research, Televeien 3, N-4879 Grimstad, Norway.
Environ Sci Technol. 2004 Jan 1;38(1):26-33. doi: 10.1021/es030065c.
Acidification of Norwegian surface waters, as indicated by elevated concentrations of sulfate and a corresponding reduction in acid neutralizing capacity and pH, is a result of emission and subsequent deposition of sulfur and nitrogen compounds. Episodic sea-salt deposition during severe weather conditions may increase the effects of acidification by mobilizing more toxic aluminum during such episodes. Changes in climatic conditions may increase the frequency and strength of storms along the coast thus interacting with acidification effects on chemistry and biota. We found that the North Atlantic Oscillation (NAO) is linked to sea-salt deposition and sea-salt induced water chemistry effects in five rivers. Particularly, toxic levels of aluminum in all rivers were significantly correlated with higher NAO index values. Further, temporal trends were studied by comparing tendencies for selected statistical indices (i.e. frequency distributions) with time. The selected indices exhibited strong correlations between the NAO index, sea-salt deposition and river data such as chloride, pH and inorganic monomeric aluminum, pointing at the influence of North Atlantic climate variability on water chemistry and water toxicity. The potentially toxic effects of sea-salt deposition in rivers seem to be reduced as the acidification is reduced. This suggests that sea-salt episodes have to increase in strength in order to give the same potential negative biological effects in the future, if acid deposition is further reduced. More extreme winter precipitation events have been predicted in the northwest of Europe as a result of climate change. If this change will be associated with more severe sea-salt episodes is yet unknown.
挪威地表水的酸化,表现为硫酸盐浓度升高以及相应的酸中和能力和pH值降低,是硫和氮化合物排放及随后沉降的结果。恶劣天气条件下的间歇性海盐沉降,可能会在这些事件中通过释放更多有毒铝来增强酸化的影响。气候条件的变化可能会增加沿海风暴的频率和强度,从而与酸化对化学和生物群的影响相互作用。我们发现,北大西洋涛动(NAO)与五条河流中的海盐沉降以及海盐引起的水化学效应有关。特别是,所有河流中铝的有毒水平与较高的NAO指数值显著相关。此外,通过将选定统计指数(即频率分布)的趋势与时间进行比较来研究时间趋势。选定的指数在NAO指数、海盐沉降和河流数据(如氯化物、pH值和无机单体铝)之间表现出很强的相关性,表明北大西洋气候变化对水化学和水毒性有影响。随着酸化程度的降低,河流中海盐沉降的潜在毒性影响似乎也在降低。这表明,如果进一步减少酸沉降,未来海盐事件的强度必须增加,才能产生相同的潜在负面生物效应。由于气候变化,预计欧洲西北部冬季降水事件将更加极端。这种变化是否会与更严重的海盐事件相关尚不清楚。