Cryle Max J, Stuthe Julia M U, Ortiz de Montellano Paul R, De Voss James J
Department of Chemistry, University of Queensland, St. Lucia, Brisbane, Australia 4072.
Chem Commun (Camb). 2004 Mar 7(5):512-3. doi: 10.1039/b315911f. Epub 2004 Jan 27.
Novel cyclopropyl containing fatty acids are good substrates for P450(BM3) catalysed hydroxylation and analysis of their oxidation products indicates the presence of a radical intermediate (maximum rebound rate 2.6 x 10(10) s(-1)) and the absence of any cationic intermediate.
新型含环丙基脂肪酸是P450（BM3）催化羟基化反应的良好底物，对其氧化产物的分析表明存在自由基中间体（最大回跳速率为2.6×10(10) s(-1)）且不存在任何阳离子中间体。
