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八(羟基)[氧代二苯二甲酸根].(对苯二甲酸)x(二甲基甲酰胺)y(水)z(或MIL - 68)，一种具有大孔杂化拓扑结构的新型钒羧酸盐：用无限无机结构单元进行网状合成？

VIII(OH)[O2C-C6H4-CO2].(HO2C-C6H4-CO2H)x(DMF)y(H2O)z(or MIL-68), a new vanadocarboxylate with a large pore hybrid topology: reticular synthesis with infinite inorganic building blocks?

作者信息

Barthelet K, Marrot J, Ferey G, Riou D

机构信息

IREM UMR CNRS 8637, Université de Versailles St Quentin, 45 Avenue des Etats-Unis, 78035 Versailles, France.

出版信息

Chem Commun (Camb). 2004 Mar 7(5):520-1. doi: 10.1039/b312589k. Epub 2004 Feb 5.

DOI:10.1039/b312589k
PMID:14973587
Abstract

V(III)(OH)[O(2)C-C(6)H(4)-CO(2)].(HO(2)C-C(6)H(4)-O(2)H)(x)(DMF)(y)(H(2)O)(z) or MIL-68 was solvothermally synthesised in a non-aqueous medium. Its structure, built up from octahedral chains connected by terephthalate linkers, exhibits large hexagonal channels containing different occluded moieties. Their irreversible removal releases a specific surface area of 603(22) m(2).g(-1)(BET).

摘要

V(III)(OH)[O(2)C-C(6)H(4)-CO(2)].(HO(2)C-C(6)H(4)-O(2)H)(x)(DMF)(y)(H(2)O)(z) 或MIL-68在非水介质中通过溶剂热法合成。其结构由通过对苯二甲酸酯连接体连接的八面体链组成，具有包含不同包合部分的大六边形通道。它们的不可逆去除释放出603(22) m(2).g(-1)(BET)的比表面积。

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