Synthesis and characterization of novel chiral sulfonato-salen-manganese(III) complex in a zinc-aluminium LDH host.
作者信息
Bhattacharjee Samiran, Anderson James A
机构信息
Surface Chemistry and Catalysis Group, Division of Physical and Inorganic Chemistry, University of Dundee, Dundee, Scotland, UK DD1 4HN.
出版信息
Chem Commun (Camb). 2004 Mar 7(5):554-5. doi: 10.1039/b315325h. Epub 2004 Feb 4.
DOI:10.1039/b315325h
PMID:14973604
Abstract
A novel heterogeneous catalyst, [Zn(2.15)Al(0.86)(OH)(6.02)]MnC(6)H(5)COOO, where [[Mn]= chiral sulfonato(-)salen-manganese(iii) complex, Na(2)MnC(20)H(22)N(2)S(2)O(12)Cl, intercalated into Zn(II)-Al(III) layered double hydroxide host], has been synthesized and found to be an effective heterogeneous catalyst for the stereoselective epoxidation of R-(+)-limonene using molecular oxygen. The catalyst could be recycled without loss of performance.
摘要
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