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杀菌剂残留对接种三种酿酒酵母菌株的白葡萄酒香气成分的影响。

Effect of fungicide residues on the aromatic composition of white wine inoculated with three Saccharomyces cerevisiae strains.

作者信息

García María Angeles, Oliva José, Barba Albero, Cámara Miguel Angel, Pardo Francisco, Díaz-Plaza Eva María

机构信息

Departamento de Química Agrícola, Geología y Edafología, Facultad de Química, Universidad de Murcia, Campus de Espinardo, 30100 Murcia, Spain.

出版信息

J Agric Food Chem. 2004 Mar 10;52(5):1241-7. doi: 10.1021/jf030546f.

Abstract

The effects of three fungicide residues (cyprodinil, fludioxonil, and pyrimethanil) on the aromatic composition (acids, alcohols, and esters) of Vitis vinifera white wines (var. Airén) inoculated with three Saccharomyces cerevisiae strains (syn. bayanus, cerevisiae, and syn. uvarum) are studied. The aromatic exponents were extracted and concentrated by adsorption-thermal desorption and were determined by gas chromatography using a mass selective detector. The addition of the three fungicides at different doses (1 and 5 mg/L) produces significant differences in the acidic fraction of the aroma, especially in the assays inoculated with S. cerevisiae, although the final contents do not exceed the perception thresholds. The lower quality wines, according to isomeric alcohol content [(Z)-3-hexen-1-ol and 3-(methylthio)propan-1-ol] are those obtained by inoculation with S. cerevisiae(syn. bayanus) and addition of cyprodinil. The addition of fungicides in the assays inoculated with S. cerevisiae (syn. bayanus) produces an increase in the ethyl acetate and isoamyl acetate contents, which causes a decrease in the sensorial quality of the wine obtained.

摘要

研究了三种杀菌剂残留(嘧菌环胺、咯菌腈和嘧霉胺)对接种了三种酿酒酵母菌株(巴氏酵母、酿酒酵母和葡萄汁有孢汉逊酵母)的阿依伦白葡萄(Vitis vinifera)葡萄酒香气成分(酸、醇和酯)的影响。香气成分通过吸附-热脱附进行提取和浓缩,并使用质量选择检测器通过气相色谱法进行测定。以不同剂量(1和5 mg/L)添加这三种杀菌剂会使香气的酸性成分产生显著差异,尤其是在接种酿酒酵母的试验中,尽管最终含量未超过感知阈值。根据异构醇含量[(Z)-3-己烯-1-醇和3-(甲硫基)丙-1-醇]判断,质量较低的葡萄酒是通过接种巴氏酵母并添加嘧菌环胺获得的。在接种巴氏酵母的试验中添加杀菌剂会使乙酸乙酯和乙酸异戊酯含量增加,这导致所获得葡萄酒的感官质量下降。

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