Feed Research Institute, Chinese Academy of Agricultural Sciences, Beijing 100081, China.
State Key Laboratory for Biology of Plant Diseases and Insect Pests, Institute of Plant Protection, Chinese Academy of Agricultural Sciences, Beijing 100193, China.
Molecules. 2020 Nov 28;25(23):5596. doi: 10.3390/molecules25235596.
Triazole pesticides are widely used to control grapevine diseases. In this study, we investigated the impact of three triazole pesticides-triadimefon, tebuconazole, and paclobutrazol-on the concentrations of wine aroma compounds. All three triazole pesticides significantly affected the ester and acid aroma components. Among them, paclobutrazol exhibited the greatest negative influence on the wine aroma quality through its effect on the ester and acid aroma substances, followed by tebuconazole and triadimefon. Qualitative and quantitative analysis by solid-phase micro-extraction gas chromatography coupled with mass spectrometry revealed that the triazole pesticides also changed the flower and fruit flavor component contents of the wines. This was attributed to changes in the yeast fermentation activity caused by the pesticide residues. The study reveals that triazole pesticides negatively impact on the volatile composition of wines with a potential undesirable effect on wine quality, underlining the desirability of stricter control by the food industry over pesticide residues in winemaking.
三唑类农药被广泛用于防治葡萄病害。在本研究中,我们调查了三种三唑类农药(三唑酮、戊唑醇和氯苯嘧啶醇)对葡萄酒香气化合物浓度的影响。这三种三唑类农药均显著影响了酯类和酸类香气成分。其中,氯苯嘧啶醇通过对酯类和酸类香气物质的影响,对葡萄酒香气质量表现出最大的负面影响,其次是戊唑醇和三唑酮。通过固相微萃取气相色谱-质谱联用的定性和定量分析表明,三唑类农药还改变了葡萄酒的花香和果香成分含量。这归因于农药残留引起的酵母发酵活性的变化。该研究表明,三唑类农药对葡萄酒的挥发性成分有负面影响,可能对葡萄酒质量产生不良影响,这凸显了食品行业在酿酒过程中更严格控制农药残留的必要性。