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Orientational phase transition and the solvation force in a nematic liquid crystal confined between inhomogeneous substrates.

作者信息

Kondrat S, Poniewierski A, Harnau L

机构信息

Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.

出版信息

Eur Phys J E Soft Matter. 2003 Feb;10(2):163-70. doi: 10.1140/epje/e2003-00020-3.

Abstract

A nematic liquid crystal confined between two identical flat solid substrates, with an alternating stripe pattern of planar and homeotropic anchoring, is studied in the framework of the Frank-Oseen theory. By means of numerical minimization of the free energy functional we study the effect of the sample thickness D on the location of the phase transition between a uniform alignment, either planar or homeotropic, and a distorted nematic texture. The solvation force f due to distortions of the nematic director is also studied. It is found that f is always attractive, and for D small compared to the periodicity of the surface structure it exhibits two distinct asymptotic behaviors: f approximately -D(-1/2) or f approximately -D(-1), depending on the relation between D and the extrapolation lengths.

摘要

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